As for Leucine/Isoleucine I have read studies that show that it alone prevents protein degradation as well as promoted protein synthesis, whereas Glutamine supplementation did not. I do agree that with protein supplementation it may not be necessary. But if you were to take a single amino, I would prefer this over the rest.
As for NO supps, I take have an EndoRush before every workout. Not because I believe it promotes hypertrophy, I know this is false. I like the feeling mentally and the pump. If I enjoy the way I feel during a workout I believe psychologically it can help you that much more. That is important as well IMO, even though one can train just as effectively without it. If you don't have the money I would not buy it for the reasons stated by KM and tim
The most important thing to remember is that no supplement should replace food, that should be the backbone and standard for your bodybuilding goals. Supplements are just that, they are to supplement your diet not replace it. Eat big, get big. Simplistic but a rather logical approach.